Acetaldehyde is a chemical that is produced when sugar is burned. Internal studies conducted by cigarette maker Phillip Morris revealed that adding acetaldehyde to nicotine significantly increases the desire to smoke.
While patches and gum may help to stave off a craving for nicotine, they don't touch the acetaldehyde.
It is no coincidence that it is harder to resist smoking when you are drinking a beer: once the acetaldehyde in your system is activated by the beer, you will crave more, in the form of a cigarette.